Effect of iron content on permeability and power loss characteristics of Li0.35Cd0.3Fe2.35O4 and Li0.35Zn0.3Fe2.35O4

Substituted lithium ferrites having the chemical formula, Li_0.35Cd_0.3Fe_2.35O₄ and Li_0.35Zn_0.3Fe_2.35O₄, with different iron (metal) contents (2, 4, 6, 8 and 10) in wt% have been prepared by solid-state technique. Complex permeability and power loss of all samples have been measured by network analyser in the frequency range of 50–5000 kHz. Magnetic properties like saturation magnetization, coercivity, retentivity have been measured by vibrating sample magnetometer (VSM). The permeability of cadmium doped lithium ferrites exhibited higher values than zinc doped lithium ferrites. The power loss of cadmium doped lithium ferrites is lesser as compared to zinc doped lithium ferrites in the frequency range of 50–5000 kHz and at flux density of 10 mT. The behaviour of power loss with flux density has been found near about same for both series. Magnetic and power loss behaviour of the samples suggest that a small amount of Fe content can improve the properties of ferrite samples for microwave devices.     

Preparation of mixed (Cd,Bi)S composite thin films via surfactant facilitated electrodeposition process and their photoelectrochemical characterization

In the present investigation we explored possibilities of preparing mixed CdS–Bi₂S₃ composite thin films of nanodimensions using a single step surfactant facilitated electrochemical process from aqueous solutions containing different colloidal concentrations of CdS and Bi₂S₃ particles. As deposited composite thin films has been characterized on the basis of SEM, AFM and XRD studies for determination of their surface morphology, surface roughness and grain size. Photoelectrochemical characterization of these composite materials has been carried out on the basis of photopotential, current–voltage (I–V) characteristics under dark and illumination conditions and photoaction spectral studies. Attempt has also been made to estimate the resistance of these composite materials towards their electrochemical corrosion. As prepared mixed (Cd,Bi)S composite semiconductor film exhibits substantial improvement in their photoelectrochemical properties.     

Study of electroless template synthesized ZnSe nanowires and its characterization

In this work, the successful synthesis of ZnSe nanowires using alumina template by simple and facile electroless template technique has been reported. Morphological characterization of the synthesized nanowires has been done by X-ray diffraction (XRD) and scanning electron microscopy (SEM) measurements. The optical characterizations were conducted by UV–visible and time resolved photo-luminescence. Grain size of synthesized ZnSe nanowires was also calculated using the XRD results. The calculated crystallite size was found to be 6.80 nm. SEM analysis confirms the fabrication of nanowires successfully and it also confirms the size of the nanowires as per the template parameters. The calculated band gap value of 3.03 eV shows the origin of quantum confinement effect in ZnSe nanowires even at the 100 nm scale. The time resolved photoluminescence result indicates that the ZnSe nanowires can be a promising material for luminescent applications in micro-second time domain.     

Multiwall carbon-nanotube-doped ion conducting polymer electrolyte for electrochemical application

Electrical, structural and optical properties of a composite containing a polymer electrolyte (namely polyethylene oxide complexed with sodium iodide) and multiwall carbon nanotube (MWCNT) are reported. The films of these composites were ‘solution casted’ using the viscous solution of polyethylene oxide (PEO) complexed with sodium iodide (NaI) in desired ratios and characterised using various techniques. The conductivity versus composition plot in PEO:NaI shows conductivity maxima at 12?wt% NaI concentration while in MWCNTs doped polymer electrolyte it occurs at 40?wt% MWCNTs concentration. The surface morphology by scanning electron microscopy (SEM) shows the enhancement in amorphous reason by MWCNTs doping which is a well-known favourable condition for conductivity enhancement. The differential scanning calorimetry shows that dispersal of MWCNTs reduces the crystallinity of polymer electrolyte that is well-supported by our polarised optical micrographs and SEM measurements.     

Assessment of empirical formulas for prediction of the effects of projectile impact on concrete structures

The prediction of the response of structures subjected to projectiles impact may often be accomplished by means of empirical or semi‐empirical formulas available in the technical literature, which address mainly cases of relevance in engineering practice in terms of the observed failure modes. The paper presents an evaluation of the performance of the equations most widely used in predictions of penetration, scabbing and perforation of concrete and rock structures by comparing the predicted results with experimentally observed response and with the results of detailed numerical analyses employing the truss‐like Discrete Element Method (DEM). Numerical DEM predictions were shown to be close to the experimentally determined responses of concrete plates subjected to impact throughout the range of velocities examined and were also consistent with the empirical formulas. In all cases the authors attempted to quantify the uncertainty inherent both in the predictions of empirical formulas and of the numerical analysis.     

Synthesis of nano-structured 3C-SiC by carbothermal reduction of silicon bearing gel and carbon soot

Nano-sized 3C-SiC was synthesized using sol-gel method. The silica bearing sol was prepared using fumed silica and alkaline ethylene glycol which on hydrolysis resulted in a gel. The gel was mixed with nano-sized carbon particles (obtained from soot) and heat treated in 1300-1580 °C temperature range. The formation of 3C-SiC began at ~ 1400 °C and at 1580 °C it was observed to be the major phase while small amount of 2H-SiC was also present. The silicon carbide synthesized between 1400 and 1580 °C had particles in 30-50 nm range and crystallite size between 15 and 17 nm.     

Transient dynamic analysis of higher order sandwich and composite arches

A higher order refined model with isoparametric elements is proposed to study the transient dynamic response of laminated arches/curved beams. The strain field is modeled through cubic axial, cubic transverse shear and linear transverse normal strain components. As the cross-sectional warping is accurately modeled by this theory, the shear correction factor is rendered redundant. The stress–strain relationship is derived from an orthotropic lamina in a three-dimensional state of stress, so that angle-ply laminates can be studied through one-dimensional elements. Consistent mass matrix is constituted for the equation of motion, which is solved by Newmark integration scheme. The higher order formulation is validated with available results and subsequently applied to arches with various curvatures, aspect ratios, boundary conditions, loadings and lamination schemes to evaluate its transient dynamic performance and suitable conclusions are drawn.     

Cognitive Radio Concept and Challenges in Dynamic Spectrum Access for the Future Generation Wireless Communication Systems

Recently, the Dynamic Spectrum Access (DSA) techniques are proposed to solve the problem of spectrum scarcity and help to use the limited spectrum resource as effectively as possible. The current ongoing spectrum reform opens up the possibilities to exploit the DSA techniques. This paper aims to provide a critical review on the various ongoing efforts towards the use of DSA concept for the frequency management of future wireless communications systems, especially from the Cognitive Radio (CR) perspective. The CR aims for an efficient and dynamic access to the spectrum, and provides a new method of spectrum management. This paper also highlights the various challenges associated with CR in order to realize the concept of DSA.     

CdTe quantum dots and polymer nanocomposites for x-ray scintillation and imaging

Investigations are reported on the x-ray scintillation and imaging application of CdTe quantum dots (QDs) and their polymer nanocomposites. Aqueous CdTe QDs with emissions ranging between 510 and 680 nm were prepared and incorporated into polyvinyl alcohol or polymethyl methacrylate polymer matrices. The x-ray luminescent properties were evaluated and a resolution of 5 lines∕mm was obtained from the nanocomposite films. Additionally, the fast decay time, nonafterglow, and superior spectral match to conventional charge coupled devices, show that CdTe QD nanocomposites have high promise for x-ray imaging applications.